Source[wall.alphacoders.com]
Total Achievements: (50)
100% completion time: ~10 hours (Varies).
Difficulty modes:

• Easy
  
• Regular
  
• Hard
  
• Master (1st Walkthrough, recommended)

New Game+: No
Missables: Yes
Mode: Single-Player, FPS

Achievement Types:
1) Story Related: (20)
2) Collectables: (3)
3) Secondary Objectives: (24)
4) Online: (3)

This game is a fairly simple 100%, we only need to do one walkthrough in Master difficulty of this game and then lastly all multiplayer achievements. It is also not a long game to do and there is clean-ups on chapter select and if you follow this guide you will earn all achievements with no problems.

You will know when you did the game on Master difficulty when there is a yellow icon but you will see it on the result screen even. The same goes to blue icons of collectables and the result screen after completing each missions.

There are 46 total pilot helmet and 8 BT-7274 loadouts collectables on this game, these are straight-forward as each level missions has them. When you don't have one you can choose chapter select and find them all progress are saved when you find certain items it includes pilot helmets. The blue icon is your collectable meter. As for BT-7274, these will be useful in certain achievements so make use of those. Not only you get collectable achievement after all 8 are collected but you get to earn other achievements with it, these are missable but can be found back when you select chapters.

For a better organised checklist of Steam Achievements, here is the Steam guide very well-done by Fojabass which unlike my other checklist is not needed for me to make one so check this well-structured guide and give him a deserved attention and awards.
https://steamcommunity.com/sharedfiles/filedetails/?id=2236502179

Before Playing: When doing this game on Master difficulty, there will be a difficult spike when doing the Titan miscellaneous and other achievements but some can be possible to unlock achievements on Master. What you can do to ease this is by dying in Master and as the screen turns grey immediately switch in-game menu to easy, making the game think your on Master but your playing on Easy now. However, if you died again on Easy, switch back to Master the same way and respawn, keep repeating the process all over again if this happens.
https://www.youtube.com/watch?v=uvpPyw_zFAk&t

!! Warning: Spoilers ahead !!

Source[dannygardner.artstation.com]

1) Missions: The Pilot's Gauntlet, BT-7274, Blood and Rust
2) Pilot Helmets: 6/46
3) BT's Loadouts: 2/8
4) Achievements: 10/50
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Pilot Helmet #1: Near the end of the Gauntlet you must get up to where the floating structure platform is, a helmet will be waiting for you.

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The Student...
Beat Pilot Anderson's Gauntlet ghost recorder time
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Achievement #1: Pilot Anderson's best time is 56.65s. In the Gauntlet, you must beat his time lower than that but this should be easy. Destroy all 15 enemy dummies and use wall running as well as timing your jumps, however this should be perfect for the other achievement so unless your skilled and masterful you will have much time to practise doing this.

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...Becomes the Master
Place in the top 3 on the Gauntlet scoreboard
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Achievement #2: Pilot F[]kada's best time is 33.65s. Along with The Student... Achievement, this will be earned also but this will take a while since it's kind of tricky, use your Ghost too for improvement. I recommend this video by Gamesager.

EPG is at the top where you shoot the targets.
Arc Grenades & EVA-8 Auto at the next area before running through the course, of course you may replace the EVA-8 Auto for R-201 if you want. I hit a time of 32.10s but by following this video it should help.
https://www.youtube.com/watch?v=G8eOoO8w1_k

After you're done, move on to the next area.

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The Graduate
Complete training
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Achievement #3: Story Related. After finishing the training, you will be teleported to another area, having an achievement unlocked for you.


Pilot Helmet #2: After the death of your Captain, not too long you will wallrun two times until you reach to a drop pod, grab the helmet.

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Apex Predator
Perform a melee takedown while cloaked in the Campaign
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Achievement #4: While you have a set of grunts to kill near the cliff, use your [middle] mouse button to execute them, as long as you killed them with it you will unlock this achievement.

Pilot Helmet #3: After grabbing the second battery, you will slide down the dirt slope until you see on the front side of the helmet, jump and wallrun to it.

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BT Prime
Fully Powered BT-7274
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Achievement #5: Story Related. Power up BT when you insert his third battery slot.

BT Loadout #1 – Expedition: First loadout weapon choice, to look into details press your designed key. What is important are the light orange yellow highlighted which are needed against enemy Titans for achievements.


Make sure to keep Lt. Shaver and Lt. Freeborn alive, if you can't find one of them then restart the whole mission.

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Cowboy Up
Rodeo an enemy Titan in the Campaign
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Achievement #6: Have one enemy Titan at low HP, then go to them to enable yourself in Rodeo mode, after destroying the Titan this achievement unlocks.

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You can be my Wingman anytime
Destroy an enemy Titan as a Pilot in the Campaign
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Achievement #7: This is also done along with the Cowboy Up Achievement. The Titan must explode along in low HP.

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Excessive Force
Destroy a Titan with your Burst Core in the Campaign
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Achievement #8: When you can use your Burst Core, find a Titan and weaken his health then use the Burst Core to destroy it with your rapid firing machine gun.

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Close Shave
Keep Lt. Shaver and Lt. Freeborn Alive
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Achievement #9: Missable. After destroying all IMC Titans while keeping your two Lieutenants alive, if Lt. Shaver thanks you for the assist or two of them stationing themselves then your good to go thus the achievement unlocks. Utilise your arsenal like the rockets, vortex shield, and Burst Core.

BT Loadout #2 – Tone: You should find it inside before your right side.

Pilot Helmet #4: Immediately after entering the tunnel entrance to inside, look to your left side that is the helmet behind the grate but before you exit out BT-7274 you must avoid the corrosive sludge water on the ground so find a safe place by the jumping onto the pipe and then to the top of the next pipe by run climbing it.

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Fire Everything!
Destroy a Titan with your Salvo Core in the Campaign
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Achievement #10: Using your newly acquired Tone loadout, damage one of the two Titans with your attacks and then use the Salvo Core to fire a barrage of missiles on the Titan, remember your Core bar never resets when switching to another.

Pilot Helmet #5: When your tasked to open the flood gates, you need to go to the tank at the top after killing all enemies jump to the pipe and then double jump to the top tank.

Pilot Helmet #6: After finding friendly units, go to your left and grab the helmet.

1) Missions: Blood and Rust, Into the Abyss
2) Pilot Helmets: 18/46
3) BT's Loadouts: 4/8
4) Achievements: 18/50
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Pilot Helmet #7: After helping them fight off the high ground IMCs, you must enter the next gate which will have more enemies, after dealing with them look to your left as the helmet is at the very top of the pipe. Wallrun towards it so you can reach the pipe.

Pilot Helmet #8: Entering the next area is a yellow pipe in front of you, jump up high and elevate yourself until you find a helmet on the very top. You must wallrun also.

Pilot Helmet #9: Get to the very top on the next area where the sludges are, the helmet is visible next to the robot who is doing some repair to the metal, wallrun to the top once again and the helmet is yours though watch out for the sludge.

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Hot Mess
Defeat Kane
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Achievement #11: Story Related. After numerous attacks against Kane and destroying his Titan you will unlock the achievement.


Pilot Helmet #10: Located inside near the beginning where to your right is a small cave from the small lake, enter through it

Pilot Helmet #11: At the same area, on your left is an open wall where someone on the radio near the drop pod is talking, to your right is where the helmet is, jump to collect it.

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Off the Beaten Path
Find 10 Collectibles
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Achievement #12: After finding 10 helmets, this achievement unlocks.

BT Loadout #3 – Scorch: Easily found in the same area moving forward.

Pilot Helmet #12: While making your way shooting on enemies, you will see a pillar between on a tight hallway, do the climbing and turning until you grab on the pipe, follow the path to your right where the end has the helmet.

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Flame On!
Destroy a Titan with your Flame Core in the Campaign
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Achievement #13: Using your new Legion loadout, drop the Titan's HP to the lowest and use the core ability, this loadout is pretty good.

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Hat Trick
Destroy 3 enemy Titans with 1 Core ability in the Campaign
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Achievement #14: When you see three titans, simply die to them first because we will be switching this time to easy. Then I suggest focusing on dodging while you shoot at the enemy Titans, once all their HPs are at the lowest use your Expedition Burst Core to destroy them.

BT Loadout #4 – Brute: After the three enemy Titans destroyed, a gate door will open to have a new loadout, move to it.

Pilot Helmet #13: Move forward after your loadout to the helipad platform, on your left has a rock ledge for you to drop down to grab the helmet, drop to the water after that to respawn back up.

Now move down from the lift to try rescuing BT-7274.

Pilot Helmet #14: Wallrun to the area where BT-7274 is talking, then look on your right after turning, jump to the left of the rock so you can wallrun to the edge to collect the helmet.

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Some Shortcut!
Entered the World Foundry
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Achievement #15: Story Related. After dropping down, you will get this achievement when you enter a new area of Assembly Line where Ash starts talking.

Pilot Helmet #15: Go through every areas where you move through the line of houses, when you see coloured blue #5 that means you are at the right place. Wait for the platform to rotate two times then you jump to the highest area of the platform unless you drop down but you can find the stairs. The helmet is at the very top pipe, wall run and collect it.

Pilot Helmet #16: When Ash starts talking, get out of the framed house and when your out, move forward from the ramp to where you can wall run, then reach to the very end of the waterfall.

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Incepted
Climb the Sideways Town
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Achievement #16: Story Related. Follow your objective until you reach jump, and wall run to a new metal platform to get this achievement.

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I'm Not Locked in Here With You
Defeated the Reapers in Ash's Simulation Dome
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Achievement #17: Story Related. After fighting alongside with your Militia units and destroying few Reapers you unlock this achievement.

Escape the simulation dome and slide down to the next area.

Pilot Helmet #17: Activate the Prowler console, the helmet is at the very top from your front view. Find a way to the top by elevating yourself and then wall run to collect the helmet from the other Prowler tower.

Pilot Helmet #18: Fight through the IMCs, you go to the left where the rock is where the plates are moving, you will see the helmet there. Wall run from the plate towards the helmet.

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Angel of Death
Destroy a Titan with your Flight Core in the Campaign
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Achievement #18: Using your new Legion loadout, drop the Titan's HP to the lowest and use the core ability. You can also do this achievement when you got Northstar.

1) Missions: Into the Abyss, Effect and Cause, The Beacon
2) Pilot Helmets: 32/46
3) BT's Loadouts: 6/8
4) Achievements: 27/50
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Coup de Grace
Destroy a Mercenary Titan with a melee execution in the Campaign
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Achievement #19: Unlike Kane, you can perform melee execution on Ash, there will be two more bosses to melee with one not being executed by you so use this early opportunity to get the achievement. Press F while approaching to the boss in order to execute them so the animation plays out.

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Dust to Dust
Defeat Ash
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Achievement #20: Story Related. Defeating Ash and her Titan will unlock this achievement.


Pilot Helmet #19: Make your way to the part where flyer creatures grab one of the hostile creature, you will see the outside. The helmet is on your right side at the ground at the wall, either drop down from the top or wallrun to it.

Pilot Helmet #20: Same place, move forward to the left lamp post and jump to it.

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It Was Coming Right For Us
Kill a Caged Prowler in the Wildlife Research Labs
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Achievement #21: After obtaining the time travel device, make sure to get inside the glass caged via present day and then back to present day to kill the Prowler inside.

Pilot Helmet #21: After fighting against enemies inside the IMC building, make sure to switch back to present day and go to the elevator. Wall run to the top inside the shaft and then time travel to the past get the helmet.

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Following the Footsteps
View Anderson's first Holographic Log
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Achievement #22: Switch to past where you will see Anderson's holograph.

Pilot Helmet #22: Near the area where Anderson's log plays but instead this is the other side, switch back to the present where you can go to the other area. Wall run through the flames from the ground and grab the helmet.

Pilot Helmet #23: Where the three turrets are, switch to present day in order to dealt with the turrets and to past day destroying the. Use present then past day as well to grab the helmet on top from the cage.

Pilot Helmet #24: In this next huge area is a cryo chamber, you will find the helmets in that area. Anyways, switch to present day to grab the helmet on your front left view.

Pilot Helmet #25: Move on to the next area which you will see later the electric rope, next you need to wall run on those lit walls at past day.

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Collector
Find 25 Collectibles
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Achievement #23: Collect 25 pilot helmets and this achievement is yours.

Pilot Helmet #26: Not long, you gotta do some wall run tricks then after that do not switch to the past day if you stand on fire, be safe there and wall run your way in the present day

BT Loadout #5 – Ion: Going back to BT-7274, you will be fighting enemies both in past and present, after dealing with them, get inside where the Titan is at the past to find the next loadout on the wall.

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Face Melter
Destroy a Titan with your Laser Core in the Campaign
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Achievement #24: Using your new Legion loadout, drop the Titan's HP to the lowest and use the core ability, the laser is good enough but still lower their hp.

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Secret Plans
Complete Special Operation 217
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Achievement #25: Story Related. This is after scanning the Ark you unlock the achievement.


BT Loadout #6 – Ronin: Located at the near beginning before the toxic cloud fog, grab it to claim the loadout.

Pilot Helmet #27: Located on Substation 03 after wallrunning, destroy all enemies and get the helmet on the right of spinning turbine.

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Unlicensed Nuclear Accelerator
Find the Arc Tool
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Achievement #26:

Pilot Helmet #28: Located after you found the Arc Tool, go to the next area after using the Arc Tool on the panel and re-activate the giant turbine to then get the helmet on your right side.

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Calling CQ
Powered the Beacon
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Achievement #27: Story Related. After using the Arc Tool inside the radiation chamber you get the achievement when the Shutters are opening.

Pilot Helmet #29: When you are trying to repair a beacon, you must get to the top. On the center is where you get the helmet, disembark from your Titan and make your way up to grab the helmet to your right.

Pilot Helmet #30: Proceed to the next left side corner where you must double jump to it at the rope point. Grab the helmet after.

Pilot Helmet #31: After being thrown by BT, go to the door on your right with the Arc Tool and grab the helmet.

Pilot Helmet #32: Move forward and wall run, instead of going right you go left, then slide and jump to the other area and use the Arc Tool. Then take care of all the enemies and move up to where the helmet is.

1) Missions: The Beacon, Trial by Fire, The Ark, The Folding Weapon
2) Pilot Helmets: 44/46
3) BT's Loadouts: 8/8
4) Achievements: 39/50
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Pied Piper
Use the Arc Tool to activate a Stalker rack
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Achievement #28: Make sure to start using the Arc Tool on the panel when moving from one area to another while using the crane, this one is for making two of the Stalkers turned friendly.

Pilot Helmet #33: After moving the wall from the crane, proceed and get up to your left where the helmet is.

Pilot Helmet #34: Around 189m you move the crane, then proceed forward. After the elevator is at the top of the helmet.

Pilot Helmet #35: Moving outside is your left side, go there and the helmet is at the top when you pass the Beacon 04 building.

Before grabbing the working module from the dish, use your Arc Tool on the Stalker racks.

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Robot Army
Acquire 6 or more friendly Stalkers at the same time in the Campaign
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Achievement #29: After using your Arc Tool on all racks (3 panels), you unlock this achievement.

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4 Bars
Retrieved a working Uplink Module
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Achievement #30: Story Related. Grab the working module from the dish to unlock this achievement.

Pilot Helmet #36: Get thrown by BT once again to the top. Proceed until you see stairs in which at the corner between is a helmet.

Pilot Helmet #37: While Slone and Blisk are having a chattering, move to the underside of the Beacon Dish on your right is the helmet.

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See You at the Party
Defeated Richter
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Achievement #31: Story Related. Defeating Richter and his Titan will unlock this achievement.


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I have the Power!
Destroy a Titan with your Sword Core in the Campaign
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Achievement #32: Using your new Legion loadout, drop the Titan's HP to the lowest and use the core ability.

Pilot Helmet #38: Right after the initial fight against Titans and Commander Sarah Briggs locking the door, you need to disembark so you can grab the helmet which is on the left side of top.

Pilot Helmet #39: When Commander Sarah Briggs mentions about the lift up ahead, disembark your Titan and make your way inside the square hole to proceed getting the helmet.

BT Loadout #7 – Northstar: After the lift with Commander Sarah Briggs, immediately another loadout will be there hanging, grab it.

Pilot Helmet #40: At 372m, disembark the Titan and proceed by the right stair to grab the helmet.

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Precious Cargo
Locate the Ark
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Achievement #33: Story Related. A cutscene will appear showing the Ark, thus unlock this achievement.


Pilot Helmet #41: Jump when you are able to in order to land on the IMC Transport ship. Then jump to the right side at the pad 01where you find the helmet.

Pilot Helmet #42: When Commander Sarah Briggs shows up with her Titan, you need to jump into it, otherwise it'll close and you can't get in, jump when she shows up to claim your helmet.

Pilot Helmet #43: On another enemy ship, fight your way through. Then when you see a set of stairs go to the last one where a helmet is.

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Defanged
Defeat Viper
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Achievement #34: Story Related. Defeating Viper and his Titan will unlock this achievement.

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The Ark
Secure the Ark
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Achievement #35: Story Related. This achievement unlocks by the end.


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I know Kung Fu
Shoot and kill 3 enemies in a row while wallrunning as a Pilot in the Campaign
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Achievement #36: With your Smart Pistol MK6 obtained from the beginning, make your way to where the enemies are running towards, wall run when you have three or more on your screen locked on and fire your pistol, making this achievement unlocked.

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Power Slide
Shoot and kill 3 enemies in a row while sliding as a Pilot in the Campaign
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Achievement #37: The same goes with sliding this time to unlock this achievement, make sure to do this in the beginning.

Pilot Helmet #44: When you are outside from the first facility you were in, take care of all the hostiles. After that, ignore the two turrets shooting at you and go to where you need to reach the top for the helmet.

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Titanfall!
Call in a new BT
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Achievement #38: Story Related. Press your designated key to call in your new Titan, FS-1041.

BT Loadout #8 – Legion: After embarking on a new BT-7274 once again when replaced, you will be equipped with the Legion as your last loadout when entering inside.

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Jack of All Trades
Collect all of BT's loadouts in the Campaign
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Achievement #39: After collecting 8 loadouts, this achievement will unlock.

1) Missions: The Folding Weapon, Online
2) Pilot Helmets: 46/46
3) Achievements: 50/50
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Aim Bot
Destroy a Titan with your Smart Core in the Campaign
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Achievement #40: Using your new Legion loadout, drop the Titan's HP to the lowest and use the core ability.

Pilot Helmet #45: After the fight against the Titans and entering inside where a Legion will appear, go to the front where you need to jump up to the red pipes for the helmet.

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Annihilation
Kill 25 infantry in 2 seconds as a Titan in the Campaign
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Achievement #41: This can be done with your Scorch loadout, you will see infantry enemies exiting from the left side of the tunnels and the others on the front, wait for them to group up until you feel like it's enough of them, then release your core ability on them.

Pilot Helmet #46: The last pilot helmet is located on the very right top most on the building inside, disembark and jump up to claim your last helmet on the big pipes.

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Every Nook and Cranny
Find All Collectibles
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Achievement #42: Collecting all 46 pilot helmets will unlock this achievement.

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No Salvage
Defeat Slone
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Achievement #43: Story Related. Defeating Slone and her Titan unlocks this achievement.

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The Real Pilot's Gauntlet
Complete the rising world run
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Achievement #44: Story Related. Once you board the ship with Commander Sarah Briggs and Barker, you unlock this achievement.

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Certified Pilot
Complete the Campaign on Regular
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Achievement #45: Story Related. This achievement stacks.

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Renowned Pilot
Complete the Campaign on Hard
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Achievement #46: Story Related. This achievement stacks.

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Legendary Pilot
Complete the Campaign on Master
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Achievement #47: Story Related. Complete the game on Master difficulty to earn the other two difficulty achievements.


Time for our final three achievements to unlock, these are straightforward so there is not much to say but I must say the multiplayer is very fun against players because you got Titans and tricks to use.

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Free Association
Join a multiplayer network
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Achievement #48: You can do this by selecting Networks > My Networks > Create > Create a Network, then the achievement will unlock.

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So It Begins...
Win a multiplayer match
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Achievement #49: You can do this by selecting Play > Find Game > Private Match > Mode, Capture the Flag and change the settings that'll be the fastest for you to complete > Start Match. Lastly, you can either capture 1 or all of the enemies' flag but you are all alone so you can relax while waiting after you capture 1 flag.

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Lock and Load
Customize a multiplayer loadout
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Achievement #50: To unlock this achievement, choose any type of customisation, Pilot, Titan, or Boost and select any type.

Titanfall 2 has an excellent story and of course multiplayer, nothing beats a short but amazing short campaign of FPS in the modern era.

The achievements are not that hard but the way you need to get the Gauntlet Top 3 achievement is kind of hard but with enough practise this becomes both easy and fun to play through, and of course the Titan and gunplay is very satisfying as you get different loadout by your preference, I personally love using Ronin and Legion.


100% finished, keep it up people and good luck :)